In this paper,six compounds were separated from the extract of chebulinic by the method of silicagel chromatography.The chemical structure of six compounds were confirmed asβ-sitosterol,shikimic acid,shikimic acid methyl ester,quercetin,quercetin-3-O-rhamnoside,galic acid according to 1HNMR,13C-NMR,IR and physical and chemical properties.Among them,shikimic acid methyl ester and quercetin-3-O-rhamnoside were found in the chebulinic at first.