一步法合成铁掺杂多孔碳对盐酸米托蒽醌的去除性能研究
作者:
作者单位:

1.福建船政交通职业学院,机械与智能制造学院,福建 福州 350007;2.福建船政交通职业学院,安全与环境学院,福建 福州 350007;3.福建师范大学环境与资源学院,福建 福州 350108

作者简介:

通讯作者:

基金项目:

福建省自然科学基金项目(2023J01164);福建船政交通职业学院校科教发展基金项目(20220102)。


Study on the Removal Performance of Iron-Doped Porous Carbon Materials Synthesized by One-Step Method for Mitoxantrone Hydrochloride
Author:
Affiliation:

1.a School of Mechanical and Intelligent Manufacturing;1b. School of Safety and Environment, Fujian Chuanzheng Communications College, Fuzhou 350007, Fujian, China; 2. College of Environmental and Resource Sciences, Fujian Normal University, Fuzhou 350108, Fujian, China

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
    摘要:

    目的 抗生素与抗肿瘤药物的广泛且过度使用,致使有机药物对水体的污染态势愈发严峻,进而引发了一系列有害的生态影响,这一现象促使学术界与环保领域高度关注有效且可持续的抗生素及抗肿瘤药物在水相中的去除方法。以抗肿瘤药物盐酸米托蒽醌为例,因其具有非特异性毒性,当被排放至自然环境中,其残留污染物会对生物体及人类健康构成长期威胁。因此,尝试开发高效去除盐酸米托蒽醌的吸附剂。方法 采用一步法,通过直接煅烧前驱体乙二胺四乙酸二钠铁(EDTA二钠铁),成功制备出铁掺杂多孔碳材料,并将其应用于水体中盐酸米托蒽醌的去除试验。研究过程中,对比了不同煅烧温度(200、400、600、800 ℃)下EDTA二钠铁材料对盐酸米托蒽醌的去除效率差异;同时,运用扫描电子显微镜(SEM)、比表面积分析(BET)等多种表征手段,探究分析了不同煅烧温度下铁掺杂多孔碳的微观结构与表面性质;此外,还系统探究了不同吸附条件,包括修复材料投加量、溶液pH值以及反应温度,对600 ℃煅烧所得铁掺杂多孔碳材料(C-Fe-600)吸附盐酸米托蒽醌效率的影响。结果 当C-Fe-600投加量为0.8 g/L、反应温度为40 ℃、溶液pH值为9.0时,该材料对盐酸米托蒽醌的去除效率达到最高。进一步研究发现,C-Fe-600材料具备良好的重复利用性,在实际废水处理中,也能够高效去除盐酸米托蒽醌。结论 C-Fe-600是一种性能优越、可重复利用的吸附材料,在实际环境治理应用中具备良好的可行性与应用前景。

    Abstract:

    Objective The widespread and excessive utilization of antibiotics and anti-tumor drugs has resulted in an increasingly grave scenario of water pollution induced by organic pharmaceuticals. This, in turn, has precipitated a series of deleterious ecological repercussions. Such a phenomenon has impelled the academic community and the environmental protection domain to accord significant attention to efficacious and sustainable methodologies for the elimination of antibiotics and anti-tumor drugs from the aqueous phase. Taking mitoxantrone hydrochloride, an anti-tumor drug, for example, due to its non-specific toxicity, upon its discharge into the natural environment, the residual pollutants pose a long-term menace to organisms and human health. Therefore, this study aims to develop efficient absorbents for the removal of anti-tumor drugs such as mitoxantrone hydrochloride.Method In this investigation, by directly calcining the precursor, Ferric Disodium Ethylenediaminetetraacetate, the iron-doped porous carbon materials were successfully prepared in one step. Subsequently, this material was applied to the experiment for the removal of mitoxantrone hydrochloride from water bodies. During the course of this research, the variances in the removal efficiency of mitoxantrone hydrochloride by iron-doped porous carbon materials under disparate calcination temperatures(200, 400, 600, 800 °C) were contrasted. Concurrently, multiple characterization techniques, such as scanning electron microscopy (SEM) and specific surface area analysis(BET), were utilized to probe and analyze the microstructures and surface properties of iron-doped porous carbon materials under different calcination temperatures. Moreover, this study also systematically probed into the impacts of diverse adsorption conditions, including the dosage of the adsorbent material, the pH value of the solution, and the reaction temperature, on the adsorption efficiency of mitoxantrone hydrochloride by the iron-doped porous carbon material (C-Fe-600) obtained via calcination at 600 °C.Result The experimental outcomes reveal that when the dosage of C-Fe-600 is 0.8 g/L, the reaction temperature is 40 °C, and the pH value of the solution is 9, the removal efficiency of mitoxantrone hydrochloride by this material attains its peak. Further research uncovered that the C-Fe-600 material exhibits favorable recyclability, and in the actual treatment of wastewater, it can also effectively remove mitoxantrone hydrochloride present therein.Conclusion This fully demonstrates that C-Fe-600 is an outstanding and reusable adsorbent material, evincing promising feasibility and application prospects in practical environmental governance endeavors.

    参考文献
    相似文献
    引证文献
引用本文

蔡婉玲,吴晓云,应杭玥.一步法合成铁掺杂多孔碳对盐酸米托蒽醌的去除性能研究[J].西昌学院学报(自然科学版),2025,39(1):49-61.

复制
分享
文章指标
  • 点击次数:
  • 下载次数:
历史
  • 收稿日期:2025-01-24
  • 最后修改日期:2025-02-07
  • 录用日期:2025-02-09
  • 在线发布日期: 2025-05-16